DUPONT (AGRICULTURAL PRODUCTS) -- KROVAR I DF HERBICIDE  -- 6840-00-001-7710
<pre>=====================  Product Identification  =====================

Product ID:KROVAR I DF HERBICIDE
MSDS Date:02/17/2000
FSC:6840
NIIN:00-001-7710
Status Code:A
=== Responsible Party ===
Company Name:DUPONT (AGRICULTURAL PRODUCTS)
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:PROD INFO: 800-441-7515
Emergency Phone Num:MED EMER: 800-441-3637
Resp. Party Other MSDS Num.:DU005711
Chemtrec Ind/Phone:(800)424-9300
CAGE:UO281
=== Contractor Identification ===
Company Name:DUPONT (AGRICULTURAL PRODUCTS)
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:PROD INFO: 800-441-7515
CAGE:UO281
Company Name:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
Contract Num:SP0450-01-M-D728
CAGE:1HB45

=============  Composition/Information on Ingredients  =============

Ingred Name:BROMACIL (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL)
CAS:314-40-9
RTECS #:YQ9100000
= Wt:40.

Ingred Name:DIURON (3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA)
CAS:330-54-1
RTECS #:YS8925000
= Wt:40.
ACGIH TLV:10 MG/M3
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:INERT INGREDIENTS
= Wt:20.

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ACUTE ORAL (RAT) LD50 >2,500 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:CAUTION: HARMFUL IF SWALLOWED. HARMFUL
    IF ABSORBED THROUGH SKIN. CAUSES EYE IRRITATION. SKIN IRRITATION
    AND SENSITIZATION. - IN SKIN IRRITATION TESTS WITH RABBITS, PRODUCT
    WAS A PRIMARY SKIN IRRITANT.  IT WAS NOT A SKIN SENSITIZER IN TESTS
    WITH GUINEA PIGS. EYE (RABBIT) - A MILD EYE IRRITANT WITH EYES
    NORMAL WITHIN 7 DAYS AFTER TREATMENT.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS PRESENT IN THIS
    MATERIAL AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED
    BY IARC, NTP, OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:SKIN CONTACT MAY INITIALLY CAUSE IRRITATION OR
    RASH, EYE CONTACT MAY INITIALLY INCLUDE IRRITATION, TEARING, OR
    BLURRING OF VISION.  OVEREXPOSURE BY INHALATION, INGESTION, SKIN OR
    EYE CONTACT MAY INITI ALLY INCLUDE: SKIN IRRITATION WITH DISCOMFORT
    OR RASH; EYE IRRITATION WITH DISCOMFORT, TEARING, OR BLURRING OF
    VISION; LIVER ENLARGEMENT; SPLEEN AND THYROID EFFECTS; RED BLOOD
    CELL DESTRUCTION; OR RED UCTION OF THE BLOOD'S OXYGEN CARRYING
    CAPACITY WITH CYANOSIS (BLUISH DISCOLORATION), WEAKNESS, OR
    SHORTNESS OF BREATH.

=======================  First Aid Measures  =======================

First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT
    BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
    GIVE OXYGEN. CALL A PHYSICIAN. SKIN CONTACT: IN CASE OF CONTACT,
    IMMEDIATELY WASH  SKIN WITH SOAP AND WATER. WASH CONTAMINATED
    CLOTHING BEFORE REUSE. EYE CONTACT: IN CASE OF CONTACT, IMMEDIATELY
    FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A
    PHYSICIAN. INGESTION: I F SWALLOWED, IMMEDIATELY GIVE 2 GLASSES OF
    WATER AND INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
    UNCONSCIOUS PERSON. CALL A PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Autoignition Temp:=420.C, 788.F
Lower Limits:0.135 G/L
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2. MAY BE
    IGNITED BY HEAT OR OPEN FLAME.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WEAR
    FULL PROTECTIVE EQUIPMENT. USE WATER SPRAY. RUNOFF FROM FIRE
    CONTROL MAY BE A POLLUTION HAZARD.
Unusual Fire/Explosion Hazard:IF AREA IS HEAVILY EXPOSED TO FIRE AND IF
    CONDITIONS PERMIT, LET FIRE BURN ITSELF OUT SINCE WATER MAY
    INCREASE THE CONTAMINATION HAZARD.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SAFEGUARDS: REVIEW FIRE FIGHTING MEASURES AND
    HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE
    APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SHOVEL
    OR SWEEP UP. NEVER RE TURN TO CONTAINER FOR REUSE. SCOOP INTO BAGS
    OR BOXES WITH PLASTIC OR ALUMINUM SHOVEL. IF SPILL AREA IS ON
    GROUND NEAR VALUABLE PLANTS OR TREES, REMOVE TOP 2 INCHES OF SOIL
    AFTER INITIAL CLEAN UP.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN A WELL VENTILATED PLACE. KEEP
    CONTAINER TIGHTLY CLOSED. DO NOT STORE OR CONSUME FOOD, DRINK OR
    TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH THIS
    MATERIAL. USERS SHOULD: WASH HANDS	BEFORE EATING, DRINKING,
    CHEWING GUM, USING TOBACCO OR USING THE TOILET.
Other Precautions:AVOID BREATHING VAPORS OR MIST, AVOID BREATHING DUST.
    AVOID CONTACT WITH EYES, SKIN, OR CLOTHING. WASH THROUGHLY AFTER
    HANDLING. WASH CLOTHING AFTER USE. DO NOT STORE OR CONSUME FOOD,
    DRINK OR TOBACCO  IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH
    THIS MATERIAL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ALWAYS FOLLOW LABEL INSTRUCTIONS WHEN USING THIS
    PRODUCT. PPE REQUIRED FOR EARLY ENTRY TO TREATED AREAS THAT IS
    PERMITTED UNDER THE WORKER PROTECTION STANDARD AND THAT INVOLVES
    ANYTHING THAT HAS BEEN  TREATED, SUCH AS PLANTS, SOIL, OR WATER.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY
    CLOSED.
Protective Gloves:WATERPROOF GLOVES.
Other Protective Equipment:LONG-SLEEVED SHIRT AND LONG PANTS.
    WATERPROOF GLOVES, SHOES PLUS SOCKS, COVERALLS.
Supplemental Safety and Health
FOLLOW MANUFACTURER'S INSTRUCTIONS FOR CLEANING/MAINTAINING PPE. IF NO
    SUCH INSTRUCTIONS FOR WASHABLES, USE DETERGENT AND HOT WATER. KEEP
    AND WASH PPE SEPARATELY FROM OTHER LAUNDRY.

==================  Physical/Chemical Properties  ==================

HCC:V7
Solubility in Water:DISPERSIBLE
Appearance and Odor:BROWN SOLID. ODOR: NONE

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE
    CONDITIONS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

===================  Toxicological Information	===================

Toxicological Information:BROMACIL:THE COMPOUND IS A MODERATE SKIN
    IRRITANT, IS A MILD TO MODERATE EYE IRRITANT, BUT IS NOT A SKIN
    SENSITIZER. RABBITS ACUTELY EXPOSED VIA DERMAL ROUTE DEMONSTRATED
    NO CLINICAL SIGNS OF TOXICITY , AND NO GROSS TISSUE CHANGES WERE
    OBSERVED, AT THE HIGHEST PRACTICAL DOSE, 5,000 MG/KG.  DIURON: THE
    COMPOUND IS A SKIN IRRITANT, IS AN EYE IRRITANT, AND IS NOT A SKIN
    SENSITIZER IN ANIMALS. TOXIC EF FECTS DESCRIBED IN ANIMALS FROM
    SHORT EXPOSURES BY INHALATION, INGESTION, OR SKIN CONTACT INCLUDE:
    BLOOD EFFECTS, SPLEEN EFFECTS, THYROID EFFECTS, METHEMOGLOBINEMIA,
    AND NONSPECIFIC EFFECTS SUCH AS WE IGHT LOSS, ETC.

====================  Disposal Considerations  ====================

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION, AND DISPOSAL
    MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
    AND LOCAL REGULATIONS. REMOVE NONUSABLE SOLID MATERIAL AND/OR
    CONTAMINATED SOIL, FOR D ISPOSAL IN AN APPROVED AND PERMITTED
    LANDFILL. DO NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTE M.

===================  MSDS Transport Information  ===================

Transport Information:NOT REGULATED

=====================  Regulatory Information  =====================

SARA Title III Information:TITLE III HAZARD CLASSIFICATIONS SECTIONS
    311, 312-  ACUTE: YES, CHRONIC: YES, FIRE: NO, REACTIVITY: NO,
    PRESSURE: NO.  SARA/CERCLA REPORTABLE QUANTITY- DIURON (100 LBS).
Federal Regulatory Information:THIS PRODUCT IS REGISTERED AND
    CONTROLLED UNDER EPA/FIFRA REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.